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An Efficient Bimetallic Rhodium Catalyst for the Direct Arylation of Unactivated Arenes
Author(s) -
Proch Sebastian,
Kempe Rhett
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200604988
Subject(s) - bimetallic strip , rhodium , catalysis , aryl , halide , ligand (biochemistry) , chemistry , combinatorial chemistry , organic chemistry , alkyl , biochemistry , receptor
Together we stand : A novel N,P‐ligand‐stabilized bimetallic rhodium complex 1 accomplishes an efficient nondirected arylation of unactivated arenes. Aryl halides with several functional groups (FG) undergo these direct coupling reactions. The key to the catalytic efficiency is the bimetallic nature of the catalyst.