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Crystalline Small‐Molecule Electrolytes
Author(s) -
Zhang Chuhong,
Andreev Yuri G.,
Bruce Peter G.
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200604934
Subject(s) - lithium (medication) , electrolyte , ion , molecule , class (philosophy) , ionic bonding , electrical conductor , chemistry , chemical engineering , materials science , inorganic chemistry , crystallography , computer science , organic chemistry , engineering , composite material , psychology , electrode , artificial intelligence , psychiatry
Tunnel route : A new class of solid ionic conductors based on glymes and lithium salts is described. The structure of one example, (CH 3 O(CH 2 CH 2 O) 4 CH 3 ) 0.5 :LiBF 4 , contains two types of tunnels filled by Li + ions, which are lined by tetraglyme molecules or BF 4 − ions, respectively (see picture; Li blue, B pink, C green, O red, F purple).