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In 2 Ge 6 O 15 (OH) 2 (H 2 dien): An Open‐Framework Indate Germanate with One‐Dimensional 12‐Ring Channels
Author(s) -
Liu GuangZhen,
Zheng ShouTian,
Yang GuoYu
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200604921
Subject(s) - germanate , microporous material , octahedron , ring (chemistry) , crystallography , materials science , chemistry , crystal structure , optoelectronics , organic chemistry , doping , composite material
A microporous indate germanate , prepared under mild solvothermal conditions with an organic amine as structure‐directing agent, has a structure in which germanate layers (green) are linked by cis ‐edge‐sharing chains of In–O octahedra (pink) to form a framework with 1D 12‐ring channels (see picture).