Cationic Terminal Aminoborylene Complexes: Controlled Stepwise Insertion into MB and BN Double Bonds | Zendy

Pierce Glesni A. | Zendy; Aldridge Simon | Zendy; Jones Cameron | Zendy; GansEichler Timo | Zendy; Stasch Andreas | Zendy; Coombs Natalie D. | Zendy; Willock David J. | Zendy

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Cationic Terminal Aminoborylene Complexes: Controlled Stepwise Insertion into MB and BN Double Bonds

Author(s) -

Pierce Glesni A.,

Aldridge Simon,

Jones Cameron,

GansEichler Timo,

Stasch Andreas,

Coombs Natalie D.,

Willock David J.

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200604838

Subject(s) - cationic polymerization , terminal (telecommunication) , chemistry , stereochemistry , double bond , crystallography , medicinal chemistry , polymer chemistry , computer science , telecommunications

One thing leads to another : Reactions of the cationic BN vinylidene analogues 1 ‐[BAr F 4 ] (R=Cy, i Pr; Ar F =3,5‐(CF 3 ) 2 C 6 H 3 ) towards dicyclohexylcarbodiimide proceed by unprecedented insertion chemistry for terminal borylene complexes. Controlled, stepwise insertion into the FeB and BN bonds is demonstrated, sequentially forming four‐membered rings linked at a spirocyclic boronium center.

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