Unexpected Structures of Aluminum Oxide Clusters in the Gas Phase | Zendy

Sierka Marek | Zendy; Döbler Jens | Zendy; Sauer Joachim | Zendy; Santambrogio Gabriele | Zendy; Brümmer Mathias | Zendy; Wöste Ludger | Zendy; Janssens Ewald | Zendy; Meijer Gerard | Zendy; Asmis Knut. R. | Zendy

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Unexpected Structures of Aluminum Oxide Clusters in the Gas Phase

Author(s) -

Sierka Marek,

Döbler Jens,

Sauer Joachim,

Santambrogio Gabriele,

Brümmer Mathias,

Wöste Ludger,

Janssens Ewald,

Meijer Gerard,

Asmis Knut. R.

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200604823

Subject(s) - gas phase , aluminum oxide , materials science , oxide , phase (matter) , aluminium , crystallography , chemistry , metallurgy , organic chemistry

No family resemblance : IR photodissociation experiments and DFT optimizations implementing a genetic algorithm suggest that small aluminum oxide clusters have unusual structures in the gas phase. For example, the structure proposed for [(Al 2 O 3 ) 4 ] + (see picture; Al black, O gray) has no features in common with bulk alumina phases.

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