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A Terminal Nitride‐to‐Phosphide Conversion Sequence Followed by Tungsten Phosphide Functionalization Using a Diphenylphosphenium Synthon
Author(s) -
Fox Alexander R.,
Clough Christopher R.,
Piro Nicholas A.,
Cummins Christopher C.
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200604736
Subject(s) - phosphide , synthon , tungsten , indium phosphide , terminal (telecommunication) , materials science , chemistry , stereochemistry , metallurgy , computer science , metal , optoelectronics , gallium arsenide , telecommunications
Ligands lost, ligands gained : A terminal tungsten nitride is converted into the corresponding terminal tungsten phosphide by a one‐pot sequence of atom‐transfer reactions (see scheme). The phosphide complex is subsequently functionalized by treatment with a phosphorus‐based electrophile. The resulting phosphorus‐rich complex displays PP multiple‐bonding character.