A Terminal Nitride‐to‐Phosphide Conversion Sequence Followed by Tungsten Phosphide Functionalization Using a Diphenylphosphenium Synthon | Zendy

Fox Alexander R. | Zendy; Clough Christopher R. | Zendy; Piro Nicholas A. | Zendy; Cummins Christopher C. | Zendy

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A Terminal Nitride‐to‐Phosphide Conversion Sequence Followed by Tungsten Phosphide Functionalization Using a Diphenylphosphenium Synthon

Author(s) -

Fox Alexander R.,

Clough Christopher R.,

Piro Nicholas A.,

Cummins Christopher C.

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200604736

Subject(s) - phosphide , synthon , tungsten , indium phosphide , terminal (telecommunication) , materials science , chemistry , stereochemistry , metallurgy , computer science , metal , optoelectronics , gallium arsenide , telecommunications

Ligands lost, ligands gained : A terminal tungsten nitride is converted into the corresponding terminal tungsten phosphide by a one‐pot sequence of atom‐transfer reactions (see scheme). The phosphide complex is subsequently functionalized by treatment with a phosphorus‐based electrophile. The resulting phosphorus‐rich complex displays PP multiple‐bonding character.

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