Noncovalently Connected Frameworks with Nanoscale Channels Assembled from a Tethered Polyoxometalate–Pyrene Hybrid | Zendy

Song YuFei | Zendy; Long DeLiang | Zendy; Cronin Leroy | Zendy

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Noncovalently Connected Frameworks with Nanoscale Channels Assembled from a Tethered Polyoxometalate–Pyrene Hybrid

Author(s) -

Song YuFei,

Long DeLiang,

Cronin Leroy

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200604734

Subject(s) - polyoxometalate , pyrene , chlorobenzene , nanoporous , chemistry , crystallization , acceptor , nanotechnology , chemical engineering , materials science , polymer chemistry , organic chemistry , physics , catalysis , condensed matter physics , engineering

Porous POMs : Crystallization of a manganese‐Anderson‐type polyoxometalate (POM) derivatized with two pyrene moieties in the presence of tetrabutylammonium cations produces a nanoporous material with butterfly‐shaped channels (O red, Mo green, C black, H white, N blue). The network is held together by very weak CH⋅⋅⋅OMo interactions, but is stable to 240 °C and can absorb up to 12 wt % chlorobenzene.

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