A Room‐Temperature Liquid‐Crystalline Phase with Crystalline π Stacks | Zendy

Xu Yijin | Zendy; Leng Siwei | Zendy; Xue Chenming | Zendy; Sun Runkun | Zendy; Pan Jie | Zendy; Ford Jason | Zendy; Jin Shi | Zendy

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A Room‐Temperature Liquid‐Crystalline Phase with Crystalline π Stacks

Author(s) -

Xu Yijin,

Leng Siwei,

Xue Chenming,

Sun Runkun,

Pan Jie,

Ford Jason,

Jin Shi

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200604607

Subject(s) - mesogen , liquid crystalline , phase (matter) , materials science , layer (electronics) , crystallography , liquid crystal , atmospheric temperature range , order (exchange) , alkyl , chemical engineering , nanotechnology , chemistry , organic chemistry , thermodynamics , physics , optoelectronics , engineering , finance , economics

Well stacked : A liquid‐crystalline material with crystalline π stacks has been synthesized in which the room‐temperature liquid‐crystalline phase consists of alternating 2D‐crystalline mesogen layers and liquidlike alkyl layers. A long‐range ordered layer structure forms as a consequence of the resulting microsegregation (see picture), with the π stacks contributing to the 2D crystalline order that exists within a layer.

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