Structural Studies of Gold(I, II, and III) Compounds with Pentafluorophenyl and Tetrahydrothiophene Ligands | Zendy

Coetzee Jacorien | Zendy; Gabrielli William F. | Zendy; Coetzee Karolien | Zendy; Schuster Oliver | Zendy; Nogai Stefan D. | Zendy; Cronje Stephanie | Zendy; Raubenheimer Helgard G. | Zendy

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Structural Studies of Gold(I, II, and III) Compounds with Pentafluorophenyl and Tetrahydrothiophene Ligands

Author(s) -

Coetzee Jacorien,

Gabrielli William F.,

Coetzee Karolien,

Schuster Oliver,

Nogai Stefan D.,

Cronje Stephanie,

Raubenheimer Helgard G.

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200604592

Subject(s) - tetrahydrothiophene , chemistry , gold compounds , scrambling , ligand (biochemistry) , chelation , orange (colour) , stereochemistry , combinatorial chemistry , medicinal chemistry , organic chemistry , computer science , biochemistry , receptor , food science , algorithm

A golden opportunity was seized to prepare an unbridged, dinucleur gold(II) compound, [Au 2 (C 6 F 5 ) 4 (tht) 2 ] (tht=tetrahydrothiophene), without any stabilizing chelating ligands (see picture; Au orange, S yellow, F green, C black) and to crystallographically characterize the gold(I) and gold(III) complexes participating in this conversion. A unique ligand scrambling of the latter gold(III) compound occurs in solution.

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