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Isolation of a Copper(I) Triazolide: A “Click” Intermediate
Author(s) -
Nolte Christoph,
Mayer Peter,
Straub Bernd F.
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200604444
Subject(s) - copper , snapshot (computer storage) , steric effects , click chemistry , chemistry , computer science , acetylide , combinatorial chemistry , database , stereochemistry , organic chemistry
Click snapshot : In an aprotic medium, a copper(I) triazolide complex is synthesized from a sterically hindered copper acetylide and an organoazide (see scheme: yellow Cu, blue N, dark gray C, gray H). This result provides direct evidence for such a complex, which had previously been hypothesized.