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Dehydration‐Induced Conversion from a Single‐Chain Magnet into a Metamagnet in a Homometallic Nanoporous Metal–Organic Framework
Author(s) -
Zhang XianMing,
Hao ZhengMing,
Zhang WeiXiong,
Chen XiaoMing
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200604284
Subject(s) - dehydration , nanoporous , magnet , porosity , solvent , organic solvent , materials science , chemical engineering , crystallography , metal organic framework , chemistry , nanotechnology , organic chemistry , composite material , adsorption , physics , biochemistry , quantum mechanics , engineering
A change for the meta : On dehydration, a 3D homometallic porous organic–inorganic framework constructed from {Co 3 (OH) 2 } chains (see structure, pink Co, red O, blue N, gray C) undergoes a transition from being a single‐chain magnet into a metamagnet. Apart from the loss of solvent water molecules, the dehydration leaves the framework structure largely unchanged.