Experimental and Theoretical Evidence for Nonheme Iron(III) Alkylperoxo Species as Sluggish Oxidants in Oxygenation Reactions | Zendy

Seo Mi Sook | Zendy; Kamachi Takashi | Zendy; Kouno Tomohisa | Zendy; Murata Koji | Zendy; Park Mi Joo | Zendy; Yoshizawa Kazunari | Zendy; Nam Wonwoo | Zendy

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Experimental and Theoretical Evidence for Nonheme Iron(III) Alkylperoxo Species as Sluggish Oxidants in Oxygenation Reactions

Author(s) -

Seo Mi Sook,

Kamachi Takashi,

Kouno Tomohisa,

Murata Koji,

Park Mi Joo,

Yoshizawa Kazunari,

Nam Wonwoo

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200604219

Subject(s) - chemistry , homolysis , reactivity (psychology) , electrophile , amine gas treating , tris , oxygenate , medicinal chemistry , combinatorial chemistry , organic chemistry , radical , catalysis , biochemistry , alternative medicine , pathology , medicine

The active oxidant that oxygenates organic substrates is an iron(IV) oxo intermediate, namely, [(tpa)Fe IV (O)(CH 3 CN)] 2+ ( 2 ), which is formed through OO bond homolysis, according to experimental and computational studies on the reactivity of nonheme iron(III) alkylperoxo complex [(tpa)Fe III (OO t Bu)(CH 3 CN)] 2+ ( 1 ), which was shown to be a sluggish electrophilic oxidant that is incapable of oxygenating organic substrates. tpa=tris(2‐pyridylmethyl)amine.

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