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Nitrogen–Carbon Bond Formation from N 2 and CO 2 Promoted by a Hafnocene Dinitrogen Complex Yields a Substituted Hydrazine
Author(s) -
Bernskoetter Wesley H.,
Lobkovsky Emil,
Chirik Paul J.
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200604099
Subject(s) - hydrazine (antidepressant) , chemistry , nitrogen , carbon fibers , medicinal chemistry , organic chemistry , stereochemistry , chromatography , materials science , composite number , composite material
Hafnocene and hydrazine : The addition of two equivalents of carbon dioxide to the hafnocene dinitrogen complex 1 proved effective for the formation of nitrogen–carbon bonds directly from N 2 and CO 2 . Subsequent treatment of 2 with Me 3 SiI liberated the dicarboxylated silyl‐substituted hydrazine 3 .