Nitrogen–Carbon Bond Formation from N 2  and CO 2  Promoted by a Hafnocene Dinitrogen Complex Yields a Substituted Hydrazine | Zendy

Bernskoetter Wesley H. | Zendy; Lobkovsky Emil | Zendy; Chirik Paul J. | Zendy

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Nitrogen–Carbon Bond Formation from N 2 and CO 2 Promoted by a Hafnocene Dinitrogen Complex Yields a Substituted Hydrazine

Author(s) -

Bernskoetter Wesley H.,

Lobkovsky Emil,

Chirik Paul J.

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200604099

Subject(s) - hydrazine (antidepressant) , chemistry , nitrogen , carbon fibers , medicinal chemistry , organic chemistry , stereochemistry , chromatography , materials science , composite number , composite material

Hafnocene and hydrazine : The addition of two equivalents of carbon dioxide to the hafnocene dinitrogen complex 1 proved effective for the formation of nitrogen–carbon bonds directly from N 2 and CO 2 . Subsequent treatment of 2 with Me 3 SiI liberated the dicarboxylated silyl‐substituted hydrazine 3 .

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