Modulation of Characteristics of a Ruthenium‐Coordinated Flavin Analogue That Shows an Unusual Coordination Mode | Zendy

Miyazaki Soushi | Zendy; Ohkubo Kei | Zendy; Kojima Takahiko | Zendy; Fukuzumi Shunichi | Zendy

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Modulation of Characteristics of a Ruthenium‐Coordinated Flavin Analogue That Shows an Unusual Coordination Mode

Author(s) -

Miyazaki Soushi,

Ohkubo Kei,

Kojima Takahiko,

Fukuzumi Shunichi

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200604028

Subject(s) - ruthenium , modulation (music) , flavin group , mode (computer interface) , chemistry , combinatorial chemistry , computer science , human–computer interaction , physics , biochemistry , catalysis , enzyme , acoustics

Hallo − hallo − ! A ruthenium(II) complex ( 1 ) with the flavin analogue alloxazine (H 2 allo) has revealed that the ligand anion (Hallo − ) forms a four‐membered chelate ring. This unprecedented coordination mode of Hallo allows it to form hydrogen bonds with a complementary receptor (e.g. 2 ), allowing the effects of hydrogen bonding on the redox behavior and electronic structure of a ruthenium‐bound Hallo radical to be studied.

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