Crystalline Mo 3 VO  x   Mixed‐Metal‐Oxide Catalyst with Trigonal Symmetry | Zendy

Sadakane Masahiro | Zendy; Watanabe Nobufumi | Zendy; Katou Tomokazu | Zendy; Nodasaka Yoshinobu | Zendy; Ueda Wataru | Zendy

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Crystalline Mo 3 VO x Mixed‐Metal‐Oxide Catalyst with Trigonal Symmetry

Author(s) -

Sadakane Masahiro,

Watanabe Nobufumi,

Katou Tomokazu,

Nodasaka Yoshinobu,

Ueda Wataru

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200603923

Subject(s) - molybdenum , catalysis , oxide , metal , trigonal crystal system , vanadium oxide , vanadium , acrolein , molybdenum oxide , crystallography , materials science , inorganic chemistry , chemistry , physics , crystal structure , metallurgy , organic chemistry

Outstanding catalytic activity for the selective oxidation of acrolein (see picture) is observed with a crystalline metal oxide, Mo 3 VO x ( x ≤11.1). The catalyst is synthesized from a solution containing pentagonal units of {Mo(Mo 5 O 27 )} (blue), which further react with molybdenum and vanadium species (red) to form a 3D metal oxide.

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