[Os 3 (CO) 6 (PMe 3 ) 3 ](μ 3 ‐η 2 :η 2 :η 2 ‐C 60 )[Re 3 (μ‐H) 3 (CO) 9 ]: A Fullerene[60] Coordinated to Two Different Trinuclear Clusters | Zendy

Park Bo Keun | Zendy; Lee Chang Yeon | Zendy; Jung Jaehoon | Zendy; Lim Jung Hak | Zendy; Han YoungKyu | Zendy; Hong Chang Seop | Zendy; Park Joon T. | Zendy

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[Os 3 (CO) 6 (PMe 3 ) 3 ](μ 3 ‐η 2 :η 2 :η 2 ‐C 60 )[Re 3 (μ‐H) 3 (CO) 9 ]: A Fullerene[60] Coordinated to Two Different Trinuclear Clusters

Author(s) -

Park Bo Keun,

Lee Chang Yeon,

Jung Jaehoon,

Lim Jung Hak,

Han YoungKyu,

Hong Chang Seop,

Park Joon T.

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200603882

Subject(s) - fullerene , chemistry , spectral line , crystallography , computational chemistry , stereochemistry , organic chemistry , physics , astronomy

A buckyball sandwich : The depicted reaction produces cis ‐ 1 and cis ‐ 2 (see picture), in which the fullerene is sandwiched between two different clusters. Variable‐temperature 1 H NMR spectra reveal that cis ‐ 1 and cis ‐ 2 are interconvertible and cis ‐ 2 exists as two isomers.

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