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[Os 3 (CO) 6 (PMe 3 ) 3 ](μ 3 ‐η 2 :η 2 :η 2 ‐C 60 )[Re 3 (μ‐H) 3 (CO) 9 ]: A Fullerene[60] Coordinated to Two Different Trinuclear Clusters
Author(s) -
Park Bo Keun,
Lee Chang Yeon,
Jung Jaehoon,
Lim Jung Hak,
Han YoungKyu,
Hong Chang Seop,
Park Joon T.
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200603882
Subject(s) - fullerene , chemistry , spectral line , crystallography , computational chemistry , stereochemistry , organic chemistry , physics , astronomy
A buckyball sandwich : The depicted reaction produces cis ‐ 1 and cis ‐ 2 (see picture), in which the fullerene is sandwiched between two different clusters. Variable‐temperature 1 H NMR spectra reveal that cis ‐ 1 and cis ‐ 2 are interconvertible and cis ‐ 2 exists as two isomers.