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Structural and Compositional Control in {M 12 } Cobalt and Nickel Coordination Clusters Detected Magnetochemically and with Cryospray Mass Spectrometry
Author(s) -
Cooper Geoffrey J. T.,
Newton Graham N.,
Kögerler Paul,
Long DeLiang,
Engelhardt Larry,
Luban Marshall,
Cronin Leroy
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200603870
Subject(s) - isostructural , cobalt , nickel , mass spectrometry , chemistry , metal , crystallography , coordination complex , inorganic chemistry , crystal structure , organic chemistry , chromatography
Control, but not a freak : A series of dodecanuclear coordination clusters of Ni II and Co II with isostructural frameworks is prepared with unparalleled structural and compositional control. At different pH values, the respective clusters can be detected in solution by cryospray mass spectrometry. The positions of the metal centers in the mixed‐metal clusters are determined from the magnetic properties.