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High‐Pressure Synthesis of Crystalline Carbon Nitride Imide, C 2 N 2 (NH)
Author(s) -
HorvathBordon Elisabeta,
Riedel Ralf,
McMillan Paul F.,
Kroll Peter,
Miehe Gerhard,
van Aken Peter A.,
Zerr Andreas,
Hoppe Peter,
Shebanova Olga,
McLaren Ian,
Lauterbach Stefan,
Kroke Edwin,
Boehler Reinhard
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200603851
Subject(s) - imide , nitride , carbon nitride , materials science , high pressure , wurtzite crystal structure , diamond anvil cell , carbon fibers , ambient pressure , characterization (materials science) , diamond , crystallography , inorganic chemistry , chemical engineering , chemistry , analytical chemistry (journal) , nanotechnology , organic chemistry , composite material , polymer chemistry , engineering physics , thermodynamics , composite number , photocatalysis , physics , layer (electronics) , engineering , catalysis , hexagonal crystal system
Extreme chemistry : The carbon nitride imide C 2 N 2 (NH) is synthesized from the single‐source precursor 1‐cyanoguanidine under high‐pressure and high‐temperature conditions in a laser‐heated diamond‐anvil cell. Characterization of single crystals recovered at ambient conditions reveals that the new compound adopts a defect wurtzite structure (see picture).