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Structural Rearrangements Induced by Photoexcitation in a RbCoFe Prussian Blue Derivative
Author(s) -
Cartier dit Moulin Christophe,
Champion Guillaume,
Cafun JeanDaniel,
Arrio MarieAnne,
Bleuzen Anne
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200603829
Subject(s) - prussian blue , metastability , photoexcitation , derivative (finance) , state (computer science) , crystal (programming language) , field (mathematics) , chemistry , materials science , physics , photochemistry , excitation , computer science , mathematics , algorithm , quantum mechanics , organic chemistry , pure mathematics , electrode , financial economics , economics , electrochemistry , programming language
Light influence : The Co crystal‐field parameter was used as a probe of the photoinduced metastable state of a RbCoFe Prussian blue analogue. From the light‐induced change in this parameter, a scheme of the photoinduced structural rearrangement is proposed in which cooperative interactions within the three‐dimensional structure impose linear geometry on all Co‐NC‐Fe entities in the metastable state (see picture).