Synthesis and Electrochemical Properties of Fullerene‐Rich Nanoclusters Synthesized by Cobalt‐Catalyzed Cyclotrimerization of Bis(aryl)alkyne Fullerodendrimers | Zendy

Hahn Uwe | Zendy; Maisonhaute Emmanuel | Zendy; Amatore Christian | Zendy; Nierengarten JeanFrançois | Zendy

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Synthesis and Electrochemical Properties of Fullerene‐Rich Nanoclusters Synthesized by Cobalt‐Catalyzed Cyclotrimerization of Bis(aryl)alkyne Fullerodendrimers

Author(s) -

Hahn Uwe,

Maisonhaute Emmanuel,

Amatore Christian,

Nierengarten JeanFrançois

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200603765

Subject(s) - alkyne , nanoclusters , aryl , cobalt , electrochemistry , catalysis , dendrimer , fullerene , chemistry , polymer chemistry , molecule , materials science , combinatorial chemistry , nanotechnology , organic chemistry , electrode , alkyl

A lot of balls : Up to 24 C 60 units were assembled around a hexaphenylbenzene core by cobalt‐catalyzed cyclotrimerization of bis(aryl)alkyne fullerodendrimers (see scheme). Electrochemical investigations reveal that interactions between C 60 units within a single dendrimer molecule are extremely efficient.

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