Evidence of an Equimolar C 2 H 2 –CO 2  Reaction in the Synthesis of Carbon Nanotubes | Zendy

Magrez Arnaud | Zendy; Seo Jin W. | Zendy; Kuznetsov Vladimir L. | Zendy; Forró László | Zendy

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Evidence of an Equimolar C 2 H 2 –CO 2 Reaction in the Synthesis of Carbon Nanotubes

Author(s) -

Magrez Arnaud,

Seo Jin W.,

Kuznetsov Vladimir L.,

Forró László

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200603764

Subject(s) - carbon nanotube , carbonate , interface (matter) , point (geometry) , content (measure theory) , metal , carbon fibers , nanotechnology , materials science , chemical engineering , chemistry , organic chemistry , engineering , mathematics , aqueous solution , composite material , mathematical analysis , gibbs isotherm , geometry , composite number

Meeting point : Carbon nanotubes (CNTs) are produced by an equimolar reaction between C 2 H 2 and CO 2 (see scheme). CO 2 can be introduced as a gas or a carbonate support of the metal particles. When CaCO 3 is used, the growth of a nanotube stems from the triple‐point junction, which corresponds to the area surrounding the metal support interface where CO 2 , C 2 H 2, and the support meet.

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