[Fe(CNXyl) 4 ] 2− : An Isolable and Structurally Characterized Homoleptic Isocyanidemetalate Dianion | Zendy

Brennessel William W. | Zendy; Ellis John E. | Zendy

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[Fe(CNXyl) 4 ] 2− : An Isolable and Structurally Characterized Homoleptic Isocyanidemetalate Dianion

Author(s) -

Brennessel William W.,

Ellis John E.

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200603746

Subject(s) - homoleptic , isocyanide , chemistry , characterization (materials science) , metal , crystallography , crystal structure , stereochemistry , nanotechnology , organic chemistry , materials science

World's record : The first isolation and structural characterization of a homoleptic isocyanidemetalate dianion has been achieved with [Fe(CNXyl) 4 ] 2− (Xyl=2,6‐dimethylphenyl; see structure, Fe red, N blue, C gray). Spectral and structural data indicate that metal‐to‐isocyanide back‐bonding in this electron‐rich species is the largest ever observed in a homoleptic isocyanide complex containing only terminally bound ligands.

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