Revisiting the Electronic Ground State of Copper Corroles | Zendy

Bröring Martin | Zendy; Brégier Frédérique | Zendy; Cónsul Tejero Esther | Zendy; Hell Christian | Zendy; Holthausen Max C. | Zendy

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Revisiting the Electronic Ground State of Copper Corroles

Author(s) -

Bröring Martin,

Brégier Frédérique,

Cónsul Tejero Esther,

Hell Christian,

Holthausen Max C.

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200603676

Subject(s) - isostructural , divalent , copper , corrole , ion , oxidation state , representation (politics) , crystallography , state (computer science) , chemistry , distortion (music) , ground state , spin states , materials science , inorganic chemistry , physics , computer science , atomic physics , crystal structure , law , political science , organic chemistry , algorithm , amplifier , optoelectronics , cmos , catalysis , politics

Back in the saddle : Copper corroles do not contain a Cu III ion, but rather a well‐hidden Cu II ion. A comparative crystallographic and theoretical study (see spin‐density representation) of isostructural corroloid complexes with copper ions in different formal oxidation states suggests that the divalent state is stabilized through a saddling distortion of the corrole ligand.

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