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Formation of Mesoporous Carbon With a Face‐Centered‐Cubic Fd $\bar 3$ m Structure and Bimodal Architectural Pores From the Reverse Amphiphilic Triblock Copolymer PPO‐PEO‐PPO
Author(s) -
Huang Yan,
Cai Huaqiang,
Yu Ting,
Zhang Fuqiang,
Zhang Fan,
Meng Yan,
Gu Dong,
Wan Ying,
Sun Xiuli,
Tu Bo,
Zhao Dongyuan
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200603665
Subject(s) - copolymer , mesoporous material , amphiphile , template , materials science , polymer , cubic crystal system , carbon fibers , bar (unit) , chemical engineering , polymer science , self assembly , nanotechnology , polymer chemistry , computer science , crystallography , chemistry , organic chemistry , composite material , physics , catalysis , composite number , meteorology , engineering
From polymer templates to mesoporous materials: With the reverse amphiphilic triblock copolymer PPO‐PEO‐PPO and a resol resin precursor an organic–organic self‐assembly process leads to the formation of an ordered polymer and a carbon mesostructure with a face‐centered‐cubic Fd $\bar 3$ m symmetry and bimodal pores (see scheme). PPO=polypropylenoxide, PEO=polyethylenoxide.