Reaching the Maximum Multiplicity of the Covalent Chemical Bond | Zendy

Roos Björn O. | Zendy; Borin Antonio C. | Zendy; Gagliardi Laura | Zendy

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Reaching the Maximum Multiplicity of the Covalent Chemical Bond

Author(s) -

Roos Björn O.,

Borin Antonio C.,

Gagliardi Laura

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200603600

Subject(s) - covalent bond , multiplicity (mathematics) , bond energy , bond order , molecule , bond length , chemical bond , atomic physics , physics , sextuple bond , bond , chemistry , molecular physics , materials science , crystallography , computational chemistry , chemical physics , mathematics , geometry , quantum mechanics , finance , economics

Maxing out at six : The maximum bond order that can be achieved between two equal atoms in the periodic system is six. The picture shows the potential energy curves for the diatoms Cr 2 , Mo 2 , and W 2 , where the latter two are sextuply bonded molecules ( d =internuclear distance in atomic units).

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