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Design, Synthesis, and Spectroscopic Investigation of Zinc Dodecakis(trifluoroethoxy)phthalocyanines Conjugated with Deoxyribonucleosides
Author(s) -
Reddy Mamidi Ramesh,
Shibata Norio,
Kondo Yuki,
Nakamura Shuichi,
Toru Takeshi
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200603590
Subject(s) - deoxyribonucleosides , conjugated system , zinc , chemistry , monomer , photochemistry , fluorescence , solvent , photosensitivity , phosphorescence , polymer chemistry , organic chemistry , materials science , polymer , physics , enzyme , quantum mechanics , optoelectronics
The single life : The UV/Vis spectra together with the strong fluorescence emission of trifluoroethoxy‐substituted zinc phthalocyanines conjugated with deoxyribonucleosides (see picture) suggest that these compounds prefer monomeric forms over aggregation. Their unique photosensitivity can be controlled by the addition of base or by the solvent used.