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A New Catalytic Route for the Activation of sp‐Hybridized Carbon–Hydrogen Bonds
Author(s) -
Marciniec Bogdan,
Dudziec Beata,
Kownacki Ireneusz
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200603582
Subject(s) - organosilicon , catalysis , reagent , chemistry , carbon fibers , silicon , hydrogen bond , combinatorial chemistry , organic chemistry , polymer chemistry , materials science , molecule , composite number , composite material
Vinyl‐substituted silicon compounds react selectively with terminal alkynes in the presence of complexes containing [Ru]H and [Ru]Si bonds to form functionalized silylethynes (see picture). This reaction opens up a new catalytic route for the preparation of a class of potent organosilicon reagents for organic synthesis.