Highly Enantioselective Hydrosilylation/Cyclization of 1,6‐Enynes Catalyzed by Rhodium(I) Complexes of Spiro Diphosphines | Zendy

Fan BaoMin | Zendy; Xie JianHua | Zendy; Li Shen | Zendy; Wang LiXin | Zendy; Zhou QiLin | Zendy

Premium

Highly Enantioselective Hydrosilylation/Cyclization of 1,6‐Enynes Catalyzed by Rhodium(I) Complexes of Spiro Diphosphines

Author(s) -

Fan BaoMin,

Xie JianHua,

Li Shen,

Wang LiXin,

Zhou QiLin

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200603533

Subject(s) - hydrosilylation , enantioselective synthesis , diphosphines , rhodium , cyclopentane , catalysis , chemistry , hydroformylation , silanes , pyrrolidine , ligand (biochemistry) , optically active , organic chemistry , medicinal chemistry , combinatorial chemistry , biochemistry , receptor , silane

Highly enantioselective synthesis : The rhodium(I) complex of the chiral ligand SDP is successfully used as a catalyst for the hydrosilylation/cyclization of 1,6‐enynes with silanes. Under the optimized reaction conditions, optically active silylalkenes containing cyclopentane or pyrrolidine rings are obtained in good yields with excellent enantioselectivities (see scheme). DCE=1,2‐dichloroethane

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research