A Trimetallic Fulvalene‐Bridged Dizirconocene–Gallium Complex | Zendy

Quillian Brandon | Zendy; Wang Yuzhong | Zendy; Wannere Chaitanya S. | Zendy; Wei Pingrong | Zendy; Schleyer Paul von Ragué | Zendy; Robinson Gregory H. | Zendy

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A Trimetallic Fulvalene‐Bridged Dizirconocene–Gallium Complex

Author(s) -

Quillian Brandon,

Wang Yuzhong,

Wannere Chaitanya S.,

Wei Pingrong,

Schleyer Paul von Ragué,

Robinson Gregory H.

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200603469

Subject(s) - zirconium , gallium , crystallography , hydride , bridging (networking) , metal , crystal structure , chemistry , materials science , inorganic chemistry , computer science , metallurgy , computer network

Star GaZr : The X‐ray structure of 1 (see picture; Ga pink, Zr blue, Cl green, C gold) illustrates a new metal–metal bonding motif between gallium and zirconium atoms: a gallium atom bonded to two zirconium atoms. Spectroscopic and computational data support the presence of a bridging Zr‐H‐Zr hydride in 1 that was undetected by single‐crystal X‐ray analysis.

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