Organocatalytic One‐Pot Asymmetric Synthesis of Functionalized Tricyclic Carbon Frameworks from a Triple‐Cascade/Diels–Alder Sequence | Zendy

Enders Dieter | Zendy; Hüttl Matthias R. M. | Zendy; Runsink Jan | Zendy; Raabe Gerhard | Zendy; Wendt Bianca | Zendy

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Organocatalytic One‐Pot Asymmetric Synthesis of Functionalized Tricyclic Carbon Frameworks from a Triple‐Cascade/Diels–Alder Sequence

Author(s) -

Enders Dieter,

Hüttl Matthias R. M.,

Runsink Jan,

Raabe Gerhard,

Wendt Bianca

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200603434

Subject(s) - intramolecular force , stereocenter , domino , tricyclic , sequence (biology) , chemistry , stereochemistry , diels–alder reaction , combinatorial chemistry , organic chemistry , enantioselective synthesis , catalysis , biochemistry

Hitting the teens! Five CC bonds and eight stereocenters were formed in a one‐pot asymmetric multicomponent domino reaction, which led to the functionalized tricyclic diterpenoid‐type core structures (see scheme, IMDA=intramolecular Diels–Alder reaction).

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