Site Isolation and Epoxidation Reactivity of a Templated Ferrous Bis(phenanthroline) Site in Porous Silica | Zendy

Terry Tracy J. | Zendy; Dubois Geraud | Zendy; Murphy Andrew | Zendy; Stack T. Daniel P. | Zendy

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Site Isolation and Epoxidation Reactivity of a Templated Ferrous Bis(phenanthroline) Site in Porous Silica

Author(s) -

Terry Tracy J.,

Dubois Geraud,

Murphy Andrew,

Stack T. Daniel P.

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200603423

Subject(s) - phenanthroline , mesoporous silica , ligand (biochemistry) , ferrous , chemistry , tris , reactivity (psychology) , combinatorial chemistry , polymer chemistry , mesoporous material , organic chemistry , catalysis , biochemistry , medicine , receptor , alternative medicine , pathology

Teaching an old ligand new tricks : Attachment of a Cu I –bis(phenanthroline) complex to mesoporous silica and metal exchange create site‐isolated Fe II –bis(phenanthroline) complexes which efficiently epoxidize terminal olefins with peracetic acid (see scheme). This strategy side‐steps the formation of a Fe II –tris(phenanthroline) complex, which predominates in solution.

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