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[Mn(tmc)(O 2 )] + : A Side‐On Peroxido Manganese(III) Complex Bearing a Non‐Heme Ligand
Author(s) -
Seo Mi Sook,
Kim Ja Young,
Annaraj Jamespandi,
Kim Youngmee,
Lee YongMin,
Kim SungJin,
Kim Jinheung,
Nam Wonwoo
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200603414
Subject(s) - manganese , ligand (biochemistry) , electrophile , heme , chemistry , nucleophile , crystal structure , peroxide , combinatorial chemistry , stereochemistry , crystallography , organic chemistry , catalysis , biochemistry , receptor , enzyme
On the side : The crystal structure of a peroxido Mn III complex bearing a non‐heme ligand shows that the peroxide ligand is bound to a manganese ion symmetrically in a side‐on η 2 fashion. The complex is capable of deformylating aldehydes by a nucleophilic reaction but not capable of oxygenating substrates by an electrophilic reaction. tmc=1,4,8,11‐tetramethyl‐1,4,8,11‐tetraazacyclotetradecane.
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