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Relativistic Functional Groups: Aryl Carbon–Gold Bond Formation by Selective Transmetalation of Boronic Acids
Author(s) -
Partyka David V.,
Zeller Matthias,
Hunter Allen D.,
Gray Thomas G.
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200603350
Subject(s) - transmetalation , aryl , chemistry , carbon fibers , combinatorial chemistry , organic chemistry , catalysis , materials science , alkyl , composite number , composite material
Gilded organometallics : Carbon–gold bond formation occurs selectively and in high yields upon reaction of gold(I) bromides with arylboronic acids in the presence of Cs 2 CO 3 . The reaction is broadly tolerant of sensitive functionalities. The resulting aryl gold(I) compounds are stable to air and water.