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Self‐Assembly of Nanometer‐Scale [Cu 24 I 10 L 12 ] 14+ Cages and Ball‐Shaped Keggin Clusters into a (4,12)‐Connected 3D Framework with Photoluminescent and Electrochemical Properties
Author(s) -
Wang XinLong,
Qin Chao,
Wang EnBo,
Su ZhongMin,
Li YangGuang,
Xu Lin
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200603250
Subject(s) - polyoxometalate , halide , covalent bond , nanometre , crystallography , nanoscopic scale , photoluminescence , materials science , self assembly , electrochemistry , nanotechnology , chemistry , inorganic chemistry , catalysis , electrode , optoelectronics , organic chemistry , composite material
Bridging two traditional but distinct research areas —polyoxometalate chemistry and cuprous halide clusters—the (4,12)‐connected 3D framework (NH 4 )[Cu 24 I 10 L 12 ][PMo V 2 Mo VI 10 O 40 ] 3 has been built by covalent linkage of nanoscale Keggin anions and [Cu 24 I 10 L 12 ] 14+ clusters (see picture; L is a multidentate N‐heterocyclic ligand); it exhibits remarkable photoluminescent and electrochemical properties.