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Dioxygen Reduction at Dicobalt Complexes of a Schiff Base Calixpyrrole Ligand
Author(s) -
Givaja Gonzalo,
Volpe Manuel,
Edwards Michael A.,
Blake Alexander J.,
Wilson Claire,
Schröder Martin,
Love Jason B.
Publication year - 2007
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200603201
Subject(s) - schiff base , chemistry , ligand (biochemistry) , reduction (mathematics) , combinatorial chemistry , stereochemistry , biochemistry , receptor , geometry , mathematics
Fixed and reduced : Dicobalt complexes of a Schiff base calixpyrrole ligand adopt rigid, wedged “pacman” structures that can accommodate oxygen (see picture) and reduce it within the bimetallic molecular cleft.