Regio‐ and Chemoselective Enzymatic N‐Oxygenation In Vivo, In Vitro, and in Flow | Zendy

Winkler Robert | Zendy; Richter Martin E. A. | Zendy; Knüpfer Uwe | Zendy; Merten Dirk | Zendy; Hertweck Christian | Zendy

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Regio‐ and Chemoselective Enzymatic N‐Oxygenation In Vivo, In Vitro, and in Flow

Author(s) -

Winkler Robert,

Richter Martin E. A.,

Knüpfer Uwe,

Merten Dirk,

Hertweck Christian

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200603060

Subject(s) - in vivo , regioselectivity , oxygenation , chemistry , in vitro , enzyme , hydrogen peroxide , combinatorial chemistry , biochemistry , catalysis , medicine , biology , microbiology and biotechnology

Action by the para : Evaluation of the nitro‐group‐forming N‐oxygenase AurF in vivo, in vitro, and immobilized as a fusion protein with simply H 2 O 2 as oxidant (peroxide shunt) reveals para ‐regioselective oxygenation of aromatic amines (see scheme). This effect includes the selective oxygenation of diamino compounds.

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