trans  Influences on Hypervalent Bonding of Aryl  λ  3 ‐Iodanes: Their Stabilities and Isodesmic Reactions of Benziodoxolones and Benziodazolones | Zendy

Ochiai Masahito | Zendy; Sueda Takuya | Zendy; Miyamoto Kazunori | Zendy; Kiprof Paul | Zendy; Zhdankin Viktor V. | Zendy

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trans Influences on Hypervalent Bonding of Aryl λ 3 ‐Iodanes: Their Stabilities and Isodesmic Reactions of Benziodoxolones and Benziodazolones

Author(s) -

Ochiai Masahito,

Sueda Takuya,

Miyamoto Kazunori,

Kiprof Paul,

Zhdankin Viktor V.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200603055

Subject(s) - hypervalent molecule , isodesmic reaction , zigzag , monomer , chemistry , aryl , medicinal chemistry , stereochemistry , polymer , crystallography , molecule , alkyl , organic chemistry , mathematics , geometry , reagent

Large and small or twice moderate : Both combinations of trans influences of the substituents favor the formation of highly stable aryl λ 3 ‐iodanes ArILL′ (examples: PhI(OH)OTs and PhI(OAc) 2 ). trans influences also seem to explain why iodosylbenzene adopts an oxo‐bridged zigzag polymer structure in contrast to PhI(OH) 2 , which is monomeric.

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