Diarylprolinol Ethers: Expanding the Potential of Enamine/Iminium‐Ion Catalysis | Zendy

Palomo Claudio | Zendy; Mielgo Antonia | Zendy

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Diarylprolinol Ethers: Expanding the Potential of Enamine/Iminium‐Ion Catalysis

Author(s) -

Palomo Claudio,

Mielgo Antonia

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200602943

Subject(s) - iminium , enamine , chemistry , electrophile , steric effects , organocatalysis , nucleophile , catalysis , organic chemistry , combinatorial chemistry , computational chemistry , enantioselective synthesis

Organocatalysts based on diarylprolinol ethers mediate a broad range of reactions involving enamine or iminium‐ion activation or a combination of both. The reactions are characterized by efficient steric control of the approach of the respective electrophile/nucleophile to the enamine/iminium‐ion counterpart, thus complementing reactions involving hydrogen‐bond donors as directing key elements.

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