Towards Homoleptic Naphthalenemetalates of the Later Transition Metals: Isolation and Characterization of Naphthalenecobaltates(1−) | Zendy

Brennessel William W. | Zendy; Young Victor G. | Zendy; Ellis John E. | Zendy

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Towards Homoleptic Naphthalenemetalates of the Later Transition Metals: Isolation and Characterization of Naphthalenecobaltates(1−)

Author(s) -

Brennessel William W.,

Young Victor G.,

Ellis John E.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200602937

Subject(s) - homoleptic , synthon , transition metal , chemistry , cobalt , naphthalene , metal , inorganic chemistry , stereochemistry , organic chemistry , catalysis

Taming of the wild anions : Highly labile naphthalene complexes of formally negative‐valent later transition metals have been obtained in the form of [Co(η 4 ‐C 10 H 8 )(η 4 ‐cod)] − (see picture; cod=1,5‐cyclooctadiene) and [Co(η 4 ‐C 10 H 8 ) 2 ] − . The latter is the first structurally authenticated homoleptic bis(naphthalene)metal anion for any d‐block element and promises to be a particularly reactive synthon for the “naked” atomic cobalt anion.

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