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Enantioselective Ene Reaction of Cyclopentadiene and α,β‐Enals Catalyzed by a Diphenylprolinol Silyl Ether
Author(s) -
Gotoh Hiroaki,
Masui Ryouhei,
Ogino Hiroshi,
Shoji Mitsuru,
Hayashi Yujiro
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200602925
Subject(s) - cyclopentadiene , enantioselective synthesis , ene reaction , silylation , silyl ether , ether , chemistry , catalysis , organic chemistry
The opposite result : A diphenylprolinol silyl ether promotes an intermolecular enantioselective ene reaction of α,β‐enals with cyclopentadiene. This is the first example of cyclopentadiene acting as the ene component, and not the diene, with α,β‐enals.