A Single‐Molecule‐Magnetic, Cubane‐Based, Triangular Co 12  Supercluster | Zendy

Zeng MingHua | Zendy; Yao MinXia | Zendy; Liang Hong | Zendy; Zhang WeiXiong | Zendy; Chen XiaoMing | Zendy

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A Single‐Molecule‐Magnetic, Cubane‐Based, Triangular Co 12 Supercluster

Author(s) -

Zeng MingHua,

Yao MinXia,

Liang Hong,

Zhang WeiXiong,

Chen XiaoMing

Publication year - 2007

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200602922

Subject(s) - supercluster (genetic) , cubane , ligand (biochemistry) , phase (matter) , core (optical fiber) , molecule , physics , magnetic susceptibility , crystallography , chemistry , condensed matter physics , chemical physics , computer science , quantum mechanics , biochemistry , phylogenetics , receptor , optics , gene

Extraordinary structure : An unprecedented Co 12 supercluster in which three Co 4 O 4 cubes surround a central μ 6 ‐nitrate ligand exhibits single‐molecule magnet behavior. The picture shows the structure of the Co 12 core and the temperature dependence of the in‐phase ( χ ′, full symbols) and out‐of‐phase ( χ ′′, open symbols) components of the magnetic susceptibility at various ac frequencies.

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