Soluble Poly( p‐ phenylenevinylene)s through Ring‐Opening Metathesis Polymerization | Zendy

Yu ChinYang | Zendy; Turner Michael L. | Zendy

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Soluble Poly( p‐ phenylenevinylene)s through Ring‐Opening Metathesis Polymerization

Author(s) -

Yu ChinYang,

Turner Michael L.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200602863

Subject(s) - metathesis , polymerization , polymer chemistry , ring opening metathesis polymerisation , ruthenium , ring opening polymerization , ring (chemistry) , acyclic diene metathesis , materials science , living polymerization , catalysis , chemistry , organic chemistry , polymer , radical polymerization , composite material

Ring opening of substituted cyclophanedienes by ruthenium‐based metathesis catalysts gives soluble phenylenevinylene homopolymers of well‐defined molecular weight with an alternating cis‐trans microstructure (see picture, R=OC 8 H 17 ). The living character of this polymerization is demonstrated by controlled chain extension.

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