Polyazidopyrimidines: High‐Energy Compounds and Precursors to Carbon Nanotubes | Zendy

Ye Chengfeng | Zendy; Gao Haixiang | Zendy; Boatz Jerry A. | Zendy; Drake Gregory W. | Zendy; Twamley Brendan | Zendy; Shreeve Jean'ne M. | Zendy

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Polyazidopyrimidines: High‐Energy Compounds and Precursors to Carbon Nanotubes

Author(s) -

Ye Chengfeng,

Gao Haixiang,

Boatz Jerry A.,

Drake Gregory W.,

Twamley Brendan,

Shreeve Jean'ne M.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200602778

Subject(s) - carbon nanotube , carbon fibers , content (measure theory) , chemistry , nanotechnology , materials science , chemical engineering , mathematics , engineering , composite material , mathematical analysis , composite number

An additional azidomethyl group dramatically decreases the melting points of the corresponding azidopyrimidines. Theoretical calculations show that these polyazido compounds (see picture; N light blue, C dark blue, H white) exhibit highly promising energetic properties. 2,4,6‐Triazidopyrimidine was found to be a novel precursor to carbon nanotubes in the presence of Ni(ClO 4 ) 2 .

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