Supramolecular Receptor Design: Anion‐Triggered Binding of C 60 | Zendy

Nielsen Kent A. | Zendy; Cho WonSeob | Zendy; Sarova Ginka H. | Zendy; Petersen Bo M. | Zendy; Bond Andrew D. | Zendy; Becher Jan | Zendy; Jensen Frank | Zendy; Guldi Dirk M. | Zendy; Sessler Jonathan L. | Zendy; Jeppesen Jan O. | Zendy

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Supramolecular Receptor Design: Anion‐Triggered Binding of C 60

Author(s) -

Nielsen Kent A.,

Cho WonSeob,

Sarova Ginka H.,

Petersen Bo M.,

Bond Andrew D.,

Becher Jan,

Jensen Frank,

Guldi Dirk M.,

Sessler Jonathan L.,

Jeppesen Jan O.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200602724

Subject(s) - magenta , supramolecular chemistry , barrel (horology) , tetrathiafulvalene , chloride , chemistry , pyrrole , ion , combinatorial chemistry , stereochemistry , materials science , organic chemistry , molecule , inkwell , composite material

Seeing is believing : Treatment of a tetrathiafulvalene‐functionalized calix[4]pyrrole 1 with chloride anions in CH 2 Cl 2 produces bowl‐like receptor 1 ⋅Cl − , which is able to encapsulate C 60 in a 2:1 barrel‐like manner. The color of C 60 ⊂( 1 ⋅Cl − ) 2 (green in CH 2 Cl 2 ) differs dramatically from its constituents (yellow and magenta for 1 and C 60 , respectively), thus allowing its formation to be monitored visually.

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