Evidence of Fluoride Transfer from the Anion of [Zr{C 5 H 3 [SiMe 2 (η 1 ‐N t Bu)] 2 }] + [RB(C 6 F 5 ) 3 ] −  Complexes to the Zirconocenium Cation | Zendy

Cano Jesús | Zendy; Sudupe María | Zendy; Royo Pascual | Zendy; Mosquera Marta E. G. | Zendy

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Evidence of Fluoride Transfer from the Anion of [Zr{C 5 H 3 [SiMe 2 (η 1 ‐N t Bu)] 2 }] + [RB(C 6 F 5 ) 3 ] − Complexes to the Zirconocenium Cation

Author(s) -

Cano Jesús,

Sudupe María,

Royo Pascual,

Mosquera Marta E. G.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200602694

Subject(s) - zirconium , fluoride , cationic polymerization , chemistry , center (category theory) , ion , atom (system on chip) , crystallography , inorganic chemistry , computer science , polymer chemistry , organic chemistry , embedded system

CF bond activation : In the presence of a phosphane, deactivation of cationic zirconium complexes can occur by direct fluoride migration to the zirconium center, that is, the breaking of a CF bond—the strongest bond of organic molecules—without previous C 6 F 5 transfer to the metal atom (see picture).

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