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Structure, Stereoelectronics, and Synthetic Potential of 1,2‐Bisonio‐1,2‐bis(dialkylamino)ethenes
Author(s) -
Weiss Robert,
Huber Stefan M.,
Heinemann Frank W.,
Audebert Pierre,
Pühlhofer Frank G.
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200602693
Subject(s) - substituent , silylation , substitution (logic) , chemistry , content (measure theory) , stereochemistry , protocol (science) , computer science , organic chemistry , mathematics , programming language , catalysis , medicine , mathematical analysis , alternative medicine , pathology
The self‐activated silyl‐assisted polyonio‐substitution (SASAPOS) protocol allows the synthesis of the first representatives of 1,2‐bisonio‐1,2‐bis(dialkylamino)ethenes (see picture; DMAP=4‐dimethylaminopyridine). Depending on the onio substituent L, one of two types of structures with different stereoelectronic configurations is adopted.