Intercalation of Organic Molecules into Vanadium(IV) Benzenedicarboxylate: Adsorbate Structure and Selective Absorption of Organosulfur Compounds | Zendy

Wang Xiqu | Zendy; Liu Lumei | Zendy; Jacobson Allan J. | Zendy

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Intercalation of Organic Molecules into Vanadium(IV) Benzenedicarboxylate: Adsorbate Structure and Selective Absorption of Organosulfur Compounds

Author(s) -

Wang Xiqu,

Liu Lumei,

Jacobson Allan J.

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200602556

Subject(s) - thiophene , organosulfur compounds , intercalation (chemistry) , molecule , aniline , chemistry , vanadium , inorganic chemistry , sulfur , sulfide , crystal structure , absorption (acoustics) , crystallography , materials science , organic chemistry , composite material

A very good host : The guest acid molecules of hydrothermally synthesized [V(O)(bdc)](H 2 bdc) 0.71 (bdc=benzenedicarboxylate) are removed to give high‐quality single crystals of [V(O)(bdc)] ( 1 ). On absorption of guest molecules from the liquid phase, 1 undergoes crystal‐to‐crystal transformations (aniline: 2 ; thiophene: 3 ; acetone: 4 ). Furthermore, complex 1 also selectively absorbs thiophene and dimethyl sulfide from methane.

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