Premium
Intercalation of Organic Molecules into Vanadium(IV) Benzenedicarboxylate: Adsorbate Structure and Selective Absorption of Organosulfur Compounds
Author(s) -
Wang Xiqu,
Liu Lumei,
Jacobson Allan J.
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200602556
Subject(s) - thiophene , organosulfur compounds , intercalation (chemistry) , molecule , aniline , chemistry , vanadium , inorganic chemistry , sulfur , sulfide , crystal structure , absorption (acoustics) , crystallography , materials science , organic chemistry , composite material
A very good host : The guest acid molecules of hydrothermally synthesized [V(O)(bdc)](H 2 bdc) 0.71 (bdc=benzenedicarboxylate) are removed to give high‐quality single crystals of [V(O)(bdc)] ( 1 ). On absorption of guest molecules from the liquid phase, 1 undergoes crystal‐to‐crystal transformations (aniline: 2 ; thiophene: 3 ; acetone: 4 ). Furthermore, complex 1 also selectively absorbs thiophene and dimethyl sulfide from methane.