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Reversibly Cross‐Linked Surface‐Grafted Polymer Brushes
Author(s) -
Loveless David M.,
AbuLail Nehal I.,
Kaholek Marian,
Zauscher Stefan,
Craig Stephen L.
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200602508
Subject(s) - polymer , polymer science , polymer chemistry , kinetics , copolymer , materials science , chemistry , chemical engineering , organic chemistry , physics , quantum mechanics , engineering
Detailed brushwork : Structurally and thermodynamically similar cross‐linkers have opposite effects on the lateral resistance of grafted thin films of poly(4‐vinylpyridine) brushes. The chemically reversible changes in mechanics are influenced by the dissimilar kinetics of the cross‐linking interaction.