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Making the True “CP” Ligand
Author(s) -
Cordaro Joseph G.,
Stein Daniel,
Rüegger Heinz,
Grützmacher Hansjörg
Publication year - 2006
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200602499
Subject(s) - ligand (biochemistry) , chemistry , mathematics , computer science , biochemistry , receptor
Cyaphide attained : A high‐yielding synthesis for the first stable terminal cyaphide complex [RuH(CP)(dppe) 2 ] (dppe=bis(1,2‐diphenylphosphinoethane); see structure: P orange, Ru silver, C gray, H white) was developed from the silyl‐substituted phosphaalkyne complex [RuH(dppe) 2 (Ph 3 SiCP)]OTf (OTf=CF 3 SO 3 − ) and sodium phenoxide.
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