Insights into the Mechanism of Methanol‐to‐Olefin Conversion at Zeolites with Systematically Selected Framework Structures | Zendy

Cui ZhiMin | Zendy; Liu Qiang | Zendy; Song WeiGuo | Zendy; Wan  LiJun | Zendy

Premium

Insights into the Mechanism of Methanol‐to‐Olefin Conversion at Zeolites with Systematically Selected Framework Structures

Author(s) -

Cui ZhiMin,

Liu Qiang,

Song WeiGuo,

Wan LiJun

Publication year - 2006

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200602488

Subject(s) - olefin fiber , mechanism (biology) , zeolite , methanol , toluene , chemistry , process (computing) , hydrocarbon , computational chemistry , chemical engineering , catalysis , organic chemistry , computer science , engineering , physics , quantum mechanics , operating system

Com‐paring mechanisms : The so‐called hydrocarbon pool mechanism does not operate with zeolite ZSM‐22 in the methanol‐to‐olefin (MTO) conversion process as a result of the narrow channels (0.57 nm) in its framework structure. However, this provided a condition free of secondary reactions for detailed mechanistic studies, with H/D exchange patterns of toluene suggesting a paring mechanism.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research